Formation and redox properties of a complex of phenazine di-N-oxide with a proton

Autor:	Aleksandr E Shilov, Yu. V. Geletii, E. M. Koldasheva, Alexander F. Shestakov
Rok vydání:	1992
Předmět:	Reaction mechanism Chemistry Inorganic chemistry Phenazine Protonation General Chemistry Photochemistry Redox chemistry.chemical_compound Saturated calomel electrode Automotive Engineering Cyclic voltammetry Acetonitrile Deoxygenation
Zdroj:	Bulletin of the Russian Academy of Sciences Division of Chemical Science. 41:655-659
ISSN:	1573-9171 1063-5211
DOI:	10.1007/bf01150886
Popis:	The electrochemical properties of phenazine di-N-oxide (OPO) in acetonitrile solutions in the presence of acids were studied by the method of cyclic voltammetry (CVA). It was shown that OPO forms with a proton a complex having a 2:1 composition, its oxidation and reduction potentials being equal to 1.57 and ∼0.35 V (saturated calomel electrode), respectively. The same protonated form is also formed in the reaction of OPO+. with organic substrates, in particular with hydrocarbons and alcohols. The reaction mechanism includes a complexation of OPO+. with the substrate, followed by splitting off of a hydrogen from the complex by another OPO+· cation-radical or a proton by the initial OPO. A rapid selective deoxygenation of the protonated form of OPO by iodide ion in acetonitrile in an acid medium has been discovered.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::15a7bcb50f2def44b55e365f8285f7fd https://doi.org/10.1007/bf01150886 Zobrazit plný text záznamu Full text from SpringerLink