ChemInform Abstract: Rearrangement of Allylic Sulfoximines to Allylic Sulfinamides

Autor:	H.‐J. Gais, Dirk Lenz, Matthias Scommoda
Rok vydání:	2010
Předmět:	Allylic rearrangement Chemistry law Thermal decomposition General Medicine Medicinal chemistry Racemization Walden inversion law.invention
Zdroj:	ChemInform. 26
ISSN:	0931-7597
DOI:	10.1002/chin.199510108
Popis:	Thermolysis of the enantiomerically pure allylic sulfoximines 3a,b leads to their partial rearrangement to the isomeric allylic sulfinamides 5a,b and 6a,b, respectively, with complete retention of configuration at the S-atom. Racemization of the allylic sulfoximines 3a,b at the S-atom does not occur.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::15a5a9c42b736cc126b349252cf873c4 https://doi.org/10.1002/chin.199510108 Zobrazit plný text záznamu Plný text