Synthesis of Mesoporous Silica Gel Doped with Dysprosium and Modified with Nickel and Study of Its Selectivity in the Catalytic Hydrogenation of a Benzene and Its Derivatives
| Autor: | A. V. Bulanova, Elena O. Filippova, R. V. Shafigulin, Alexander A. Tokranov |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Cyclohexane
General Chemical Engineering chemistry.chemical_element 02 engineering and technology General Chemistry Mesoporous silica 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Ethylbenzene 0104 chemical sciences Catalysis chemistry.chemical_compound Nickel chemistry Dysprosium 0210 nano-technology Selectivity Benzene Nuclear chemistry |
| Zdroj: | Russian Journal of Applied Chemistry. 93:741-747 |
| ISSN: | 1608-3296 1070-4272 |
| DOI: | 10.1134/s1070427220050158 |
| Popis: | The work studied the hydrogenation of benzene and its derivatives on the mesoporous silica gel synthesized by the template method, doped with dysprosium and modified with nickel nanoparticles. The surface morphology and texture characteristics of the obtained sample were studied by scanning and transmission electron microscopy, X-ray phase analysis, and inductively coupled plasma mass spectrometry. The catalytic activity and selectivity of the obtained catalyst in the hydrogenation reaction of a mixture with an equal content of benzene, ethylbenzene, p-, o-xylenes in the temperature range of 100–170°С at a pressure of 3 atm was studied. It was found that the obtained catalyst selectively hydrogenates benzene in a mixture with its derivatives to cyclohexane. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink