Synthesis, structure, and properties of the complex [Cu(L)Cl] ∙ 2H2O
| Autor: | G. V. Tsintsadze, F. S. Alieva, F. O. Mamedova, F. N. Bakhmanova, R. A. Alieva, A. V. Kurbanov, A. M. Magerramov, F. M. Chyragov |
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| Rok vydání: | 2016 |
| Předmět: |
Diffraction
Ligand Chemistry General Chemical Engineering chemistry.chemical_element Ethylenediamine General Chemistry Crystal structure 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Copper 0104 chemical sciences Crystallography chemistry.chemical_compound Square pyramid Group (periodic table) Orthorhombic crystal system |
| Zdroj: | Russian Journal of Coordination Chemistry. 42:351-354 |
| ISSN: | 1608-3318 1070-3284 |
| DOI: | 10.1134/s1070328416050043 |
| Popis: | The crystal structure of copper(II) complex with the HL ligand obtained from 3-[4-carboxyphenylazo] penta-2,4-dione and ethylenediamine (En) was determined by X-ray diffraction. The crystals are orthorhombic: a = 7.329(3), b = 15.393(5), c = 18.474(7) A, V = 2084.1(12) A3, space group P212121, Z = 4, ρ(calcd.) = 1.486 g/cm3, R = 0.0441. The copper atom is coordinated by four nitrogen atoms of two En ligands and by the chlorine atom in an axial position according to the extended square pyramid geometry (4 + 1) (CIF file CCDC no. 1436882). |
| Databáze: | OpenAIRE |
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