Analytical Derivation of the Sauer-Freise Flux Equation for Multicomponent Multiphase Diffusion Couples with Variable Partial Molar Volumes
| Autor: | William J. Boettinger, Geoffrey B. McFadden, Robert F. Sekerka |
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| Rok vydání: | 2016 |
| Předmět: |
010302 applied physics
Molar Chemistry Diffusion Metals and Alloys Boltzmann–Matano analysis Thermodynamics 02 engineering and technology Classification of discontinuities 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Molar volume Volume (thermodynamics) 0103 physical sciences Materials Chemistry Flux equation Physics::Chemical Physics 0210 nano-technology Variable (mathematics) |
| Zdroj: | Journal of Phase Equilibria and Diffusion. 37:640-650 |
| ISSN: | 1863-7345 1547-7037 |
| DOI: | 10.1007/s11669-016-0500-0 |
| Popis: | The well-known Sauer-Freise flux equation is derived analytically for the general case of a multiphase, multicomponent diffusion couple with variable molar volume. Discontinuities in concentration versus distance data are specifically treated. Fluxes with respect to the local center of volume are employed if the partial molar volumes are constants. Fluxes with respect to the local center of moles are employed for the more general case of variable partial molar volumes. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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