Statistical evaluation of non-isothermal decomposition kinetics analysis methods for AIBN

Autor:	T. Provder, R. M. Holsworth, C. M. Neag
Rok vydání:	1987
Předmět:	Arrhenius equation Order of reaction Chemistry Kinetics technology industry and agriculture Thermodynamics Activation energy Decomposition Isothermal process symbols.namesake symbols Data analysis Physical chemistry Chemical decomposition
Zdroj:	Journal of Thermal Analysis. 32:1833-1842
ISSN:	1572-8943 0368-4466
DOI:	10.1007/bf01913975
Popis:	Decomposition kinetics parameters were obtained from non-isothermal DSC data for the decomposition of AIBN by two data analysis methods. A statistical evaluation of the results showed that there was no difference between the results obtained by each data analysis method and that the heating rate did not significantly affect the values of the kinetics parameters. Both data analysis methods isolate the order of reaction,n, the activation energy,E, and the Arrhenius factor,A, from a single non-isothermal scan of the decomposition reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1577a8125d58535a8045c2bbf4d56f97 https://doi.org/10.1007/bf01913975 Zobrazit plný text záznamu Full text from SpringerLink