Synthesis and self-association properties of diethynylbenzene macrocycles

Autor:	Yoshito Tobe, Koichiro Naemura, Naoto Utsumi, Kazuya Kawabata
Rok vydání:	1996
Předmět:	Chemistry Self association Organic Chemistry Drug Discovery Polymer chemistry Stacking Biochemistry
Zdroj:	Tetrahedron Letters. 37:9325-9328
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(97)82954-1
Popis:	We synthesized diethynylbenzene macrocycles (DBMs), cyclic oligomers of diethynylbenzene, having functional groups in the periphery of the macrocyclic framework and investigated their self-association properties in solution resulting from π-π stacking interaction. The tetrakis-DBM having hexadecyl ester groups showed dimerization behavior not only in chloroform-d, but also in o-dichlorobenzene-d4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1516cba37f8eb7c3b2ad2dc92b9a33e4 https://doi.org/10.1016/s0040-4039(97)82954-1 Zobrazit plný text záznamu Full Text from ScienceDirect