The fifth spectrum of platinum (Pt V): Analysis of the (5d6+5d56s)−5d56p transition array
| Autor: | V I Azarov, Robert R. Gayasov |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Nuclear and High Energy Physics
010308 nuclear & particles physics Spectrum (functional analysis) Analytical chemistry chemistry.chemical_element 01 natural sciences Atomic and Molecular Physics and Optics Spectral line Vacuum ultraviolet Wavelength chemistry Ionization 0103 physical sciences Level structure Emission spectrum Atomic physics 010306 general physics Platinum |
| Zdroj: | Atomic Data and Nuclear Data Tables. 108:154-192 |
| ISSN: | 0092-640X |
| Popis: | The spectrum of platinum was observed in the 300–2100 A wavelength region. The ( 5 d 6 + 5 d 5 6 s ) − 5 d 5 6 p transition array of four times ionized platinum, Pt V, has been investigated and 1659 spectral lines have been classified in the region of 460–1730 A. The analysis has led to the determination of the 5 d 6 , 5 d 5 6 s and 5 d 5 6 p configurations. Thirty two of 34 theoretically possible 5 d 6 levels, 45 of 74 possible 5 d 5 6 s levels and 181 of 214 possible 5 d 5 6 p levels have been established. The orthogonal operators technique was used to calculate the level structure and transition probabilities. The energy parameters have been determined by the least squares fit to the observed levels. Calculated transition probability and energy values, as well as LS -compositions obtained from the fitted parameters are presented. |
| Databáze: | OpenAIRE |
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