Alternating perpendicular 1-D channels in the supramolecular structure of the copper(II) complex [Cu(pyterpy)2](PF6)2·CH3OH·0.5 CH2Cl2 (pyterpy=4′-(4′′′-pyridyl)-2,2′:6′,2′′-terpyridine)

Autor:	Andreas F. Thünemann, Günter Reck, Werner Kraus, Dirk G. Kurth, Jesús Pitarch López
Rok vydání:	2005
Předmět:	Chemistry Inorganic chemistry Intermolecular force Supramolecular chemistry Stacking chemistry.chemical_element Crystal structure Copper Inorganic Chemistry Crystal Crystallography chemistry.chemical_compound Materials Chemistry Molecule Physical and Theoretical Chemistry Terpyridine
Zdroj:	Inorganic Chemistry Communications. 8:281-284
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2004.12.030
Popis:	The reaction of 4′-(4′′′-pyridyl)-2,2′:6′,2′′-terpyridine (pyterpy) with copper(II) yields the novel mononuclear [Cu(pyterpy) 2 ](PF 6 ) 2 complex. The crystal structure shows that the Cu(II) center is coordinated by the terpyridine domains of both pyterpy molecules, while the pyridyl tails remain uncoordinated. Intermolecular π–π stacking interactions between the cations in the crystal result in the formation of alternating 1-D linear channels which run in perpendicular directions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::14ffba520fb516f429aea482fa0de8ef https://doi.org/10.1016/j.inoche.2004.12.030 Zobrazit plný text záznamu Full Text from ScienceDirect