ChemInform Abstract: Application of Ene-Like Reactions of Aldehydes with Vinyl Ethers: Facile Assembly of Benzazocenone Intermediates for Mitomycinoids
| Autor: | Mingying Chen, Marco A. Ciufolini, Melissa V. Deaton, Dennis P. Lovett |
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| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | ChemInform. 28 |
| ISSN: | 0931-7597 |
| DOI: | 10.1002/chin.199738210 |
| Popis: | Benzazocenone intermediates for mitomycinoids are now available in only six steps. Key phases of this sequence include the ene-like reaction of 2-methoxypropene with a 2-azidophenyacetaldehyde and a novel heterocyclic ring formation/expansion reaction. |
| Databáze: | OpenAIRE |
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