Diastereoselective, Lewis acid-mediated Diels–Alder reactions of allenoic acid derivatives and 1,3-cyclopentadienes

Autor: Freya M. Harvey, Alexandra H. Heidecker, Christian Merten, Thorsten Bach
Rok vydání: 2023
Předmět:
Zdroj: Organic & Biomolecular Chemistry. 21:4422-4428
ISSN: 1477-0539
1477-0520
Popis: The stereoselectivity of the title reaction is governed by the substitution pattern within the allene substrate and by the choice of Lewis acid catalyst allowing a facile access to bicyclo[2.2.1]heptenes with an exocyclic double bond.
Databáze: OpenAIRE