Kinetics of hydrogen absorption by porous nickel in an aqueous sodium hydroxide solution

Autor:	M. V. Ulitin, O. V. Lefedova, Yu. E. Romanenko
Rok vydání:	2012
Předmět:	Nickel chemistry.chemical_compound Aqueous solution Adsorption chemistry Sodium hydroxide Kinetics Inorganic chemistry chemistry.chemical_element Physical and Theoretical Chemistry Kinetic energy Porosity Catalysis
Zdroj:	Russian Journal of Physical Chemistry A. 86:953-958
ISSN:	1531-863X 0036-0244
DOI:	10.1134/s0036024412060271
Popis:	Kinetic studies of hydrogen absorption by porous nickel catalyst establish that there are three regions on kinetic curves of the process differing in their regularities of adsorption. The dependence of the observed rate of hydrogen absorption on the adsorbate amount is formally described by a first order kinetic equation, and the absorption rate constants corresponding to distinct parts of the kinetic curve differ by 1–2 orders of magnitude. The obtained data are explained using the concept that hydrogen adsorption on nickel active centers proceeds with three forms of adsorption.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::14a3585049f352953548998b06784893 https://doi.org/10.1134/s0036024412060271 Zobrazit plný text záznamu Full text from SpringerLink