Synthesis, crystal structure and nonlinear optical property of Rb3V5O14
| Autor: | Yuebao Li, Yuejie Cui, Xing Li, Lei Han, Lingyan Zhao, Jianguo Pan |
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| Rok vydání: | 2010 |
| Předmět: |
Diffraction
Thermogravimetric analysis Materials science Crystal structure Radiation Condensed Matter Physics Electronic Optical and Magnetic Materials Ion Inorganic Chemistry Crystal Nonlinear optical Crystallography Materials Chemistry Ceramics and Composites Physical and Theoretical Chemistry Layer (electronics) |
| Zdroj: | Journal of Solid State Chemistry. 183:2759-2762 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/j.jssc.2010.09.017 |
| Popis: | The new nonlinear optical crystal Rb 3 V 5 O 14 has been synthesized by solid state reaction and characterized by single-crystal X-ray diffraction, IR and thermogravimetric analysis. The crystal Rb 3 V 5 O 14 crystallizes in the trigonal system with space P 31 m (No. 157), a = b =8.7134(12) A, c =5.2807(11) A and α =90°, β =90°, γ =120°, Z= 1, ρ =3.516 g/cm 3 . It is a layered structure that is very flat and strongly parallel to c . The V 5 O 14 layer structure consists of corner-linked square and triangular pyramids. The layers are separated by Rb + ions, which fit equally well on the V 5 O 14 layer. The Kurtz powder SHG measurement, using 1064 nm radiation, showed that the second-harmonic generation efficiency of Rb 3 V 5 O 14 is about two times that of KDP. |
| Databáze: | OpenAIRE |
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