Normal, abnormal and pseudo-abnormal reaction pathways for the imine-peroxyacid reaction

Autor: Narain D. Sharma, Derek R. Boyd, Peter B. Coulter, W.Brian Jennings, Valerie E. Wilson
Rok vydání: 1985
Předmět:
Zdroj: Tetrahedron Letters. 26:1673-1676
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)98582-4
Popis: Steric and mesomeric effects have a marked influence upon the formation of oxaziridine (normal pathway) or nitrone (abnormal pathway) products from the imine-peroxyacid reaction; n.m.r. studies of the thermal isomerization of oxaziridines to nitrones provide evidence of a pseudo-abnormal oxidation pathway.
Databáze: OpenAIRE