Preparation and Structure of [(η5-C5H5)Fe(CO){C(O)Ph}2]2Li2(2,2′-Bipyridine): A Sequential Treatment of Nucleophile Followed by Lewis Base

Autor:	Ling-Kang Liu, James Peng, Candice Huang
Rok vydání:	2002
Předmět:	chemistry.chemical_compound Bipyridine Nucleophilic addition Deprotonation Nucleophile Chemistry Stereochemistry Electrophile General Chemistry Lewis acids and bases Medicinal chemistry Sequential treatment 2 2'-Bipyridine
Zdroj:	Journal of the Chinese Chemical Society. 49:311-314
ISSN:	0009-4536
DOI:	10.1002/jccs.200200047
Popis:	Unable to elaborate (η 5 -C 5 H 5 )Fe(CO) 2 C(O)Ph by the nucleophile/electrophile sequences, the treatment of nucleophile PhLi followed by Lewis base 2,2'-bipyridine instead leads to the meaningful isolation of [(η 5 -C 5 H 5 )Fe(CO){C(O)Ph} 2 ] 2 Li 2 (2,2'-bipyridine).
Databáze:	OpenAIRE
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