Phenoxyl radical complexes of chromium(III)

Autor:	Eckhard Bill, Karl Wieghardt, Thomas Weyhermüller, Achim Sokolowski, Eberhard Bothe
Rok vydání:	1996
Předmět:	Chemistry Metals and Alloys chemistry.chemical_element General Chemistry Phenoxyl radical Photochemistry Medicinal chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Hexadentate ligand Chromium Yield (chemistry) Materials Chemistry Ceramics and Composites
Zdroj:	Chem. Commun.. :1671-1672
ISSN:	1364-548X 1359-7345
DOI:	10.1039/cc9960001671
Popis:	The hexadentate ligand 1,4,7-tris(3-tert-butyl-5-methoxy-2-hydroxybenzyl)-1,4,7-triazacyclononane, H3L, forms a very stable neutral complex [CrIIIL]·2MeCN 2 with chromium(III) which undergoes electrochemically three one-electron oxidations to yield [CrIIIL]+, [CrIIIL]2+ and [CrIIIL]3+, respectively; these contain one, two and three coordinated phenoxyl radical ligands; [CrIIIL]·2MeCN and [CrIIIL]ClO4·3MeCN are characterized by X-ray crystallography.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::143dc3f5ba636ad63c1257103f9dccbd https://doi.org/10.1039/cc9960001671 Zobrazit plný text záznamu