METHYL DIHYDROJASMONATE AND ITS STEREOISOMERS: SENSORY PROPERTIES AND ENANTIOSELECTIVE ANALYSIS

Autor:	H.-J. Bertram, Peter Werkhoff, Gerhard Krammer, Shaun P. Brennecke, M. Roloff
Rok vydání:	2002
Předmět:	Chiral column chromatography Methyl dihydrojasmonate chemistry.chemical_compound Chromatography Chemistry General Chemical Engineering Enantioselective synthesis Gas chromatography Enantiomer Chiral stationary phase Mass spectrometry High-performance liquid chromatography Food Science
Zdroj:	Food Reviews International. 18:103-122
ISSN:	1525-6103 8755-9129
Popis:	Enantiomeric methyl dihydrojasmonates (MDHJs) were separated by chiral gas chromatography (GC) and high performance liquid chromatography. Organoleptical evaluation clearly revealed that all four stereoisomers are odor-active and differ in their olfactory properties. Using enantio-multidimensional capillary GC–mass spectrometry with heptakis(2,3-di-O-methyl-6-O-tertbutyldimethylsilyl)-β-cyclodextrin as the chiral stationary phase, the direct enantioselective analysis of all four stereoisomers of MDHJ in numerous natural products was achieved for the first time.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::143b266a5c55fbcd771bfa464564a52a https://doi.org/10.1081/fri-120014353 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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