Visible-light-promoted alkylation of unsaturated MIDA boronates using Ru(bpy) 3 Cl 2 as the photoredox catalyst

Autor:	Krzysztof Durka, Marek Dąbrowski, Krzysztof Woźniak, Tomasz Kliś, Janusz Serwatowski, Marcin Kublicki
Rok vydání:	2017
Předmět:	Quenching (fluorescence) 010405 organic chemistry Chemistry Atom-transfer radical-polymerization Organic Chemistry Alkylation 010402 general chemistry Photochemistry 01 natural sciences Biochemistry 0104 chemical sciences Catalysis Drug Discovery Polymer chemistry Single crystal Visible spectrum
Zdroj:	Tetrahedron Letters. 58:2162-2165
ISSN:	0040-4039
DOI:	10.1016/j.tetlet.2017.04.075
Popis:	The development of a visible light-mediated atom transfer radical addition (ATRA) of perfluoroalkyl iodides to ethynyl-, vinyl- and allyl-MIDA boronates using the reductive and oxidative quenching of [Ru(bpy)3]Cl2 is described. Using an operationally simple and mild protocol, the corresponding MIDA boronates containing perfluoroalkyl groups were obtained in moderate to high yields. The structures of three products were confirmed by single crystal X-ray diffraction studies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::143199eb3df1570827d4a9e273022de5 https://doi.org/10.1016/j.tetlet.2017.04.075 Zobrazit plný text záznamu Full Text from ScienceDirect