Silyl–Silylene Interplay in Cationic PSiP Pincer Complexes of Platinum

Autor:	Jia Zhou, Justin R. Walensky, Billy J. McCulloch, Jessica C. DeMott, Weixing Gu, Oleg V. Ozerov, Mitchell D. Goshert, David E. Herbert
Rok vydání:	2015
Předmět:	Silylation Ligand Organic Chemistry Silylene Cationic polymerization chemistry.chemical_element Photochemistry Pincer movement Inorganic Chemistry chemistry.chemical_compound chemistry Polymer chemistry Carborane Physical and Theoretical Chemistry Platinum
Zdroj:	Organometallics. 34:3930-3933
ISSN:	1520-6041 0276-7333
DOI:	10.1021/acs.organomet.5b00596
Popis:	Herein we report the synthesis and spectroscopic observation of a Pt complex featuring a P2Si═ ligand containing a central silylene donor connected to phosphines via two o-arylene linkers. Species of the type (P2Si═)PtR undergo a net 1,2-migration of R from Pt to Si, which leads to highly unsaturated Pt cations displaying only a very distant interaction with the weakly coordinating carborane anion.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::14271ed1761299a967bfa2352db1b1f9 https://doi.org/10.1021/acs.organomet.5b00596 Zobrazit plný text záznamu