Tris(dimethylammonium) hydrogen α-dodecamolybdosilicate
Autor: | Zong-Jun Ku, Ke-Li Zhang, Zhong-Hai Zhang |
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Rok vydání: | 2007 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E Structure Reports Online. 63:m878-m880 |
ISSN: | 1600-5368 |
DOI: | 10.1107/s1600536807007192 |
Popis: | The title compound, (C2H8N)3[HSiMo12O40], has an α-Keggin heteropolyoxo anion with a central SiO4 tetrahedron and three dimethylammonium cations. The asymmetric unit contains one Si atom and one O with site symmetry \overline{3}m, two Mo atoms, seven O atoms, two C atoms and one N atom with site symmetry m, and one Mo and three O atoms in general positions. These cations and anions are linked via N—H...O hydrogen bonds, forming a layer structure. |
Databáze: | OpenAIRE |
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