On the reactivity-selectivity relationship in the solvolysis of several reactive alkyl halides

Autor:	Zvi Rappoport, Rachel Ta-Shma
Rok vydání:	1982
Předmět:	chemistry.chemical_classification Chemistry Organic Chemistry Drug Discovery Halide Reactivity (chemistry) Solvolysis Photochemistry Selectivity Biochemistry Medicinal chemistry Alkyl Ion
Zdroj:	Tetrahedron Letters. 23:781-784
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)86948-8
Popis:	In contrast to previous reports, the selectivities of four carbenium ions R + towards N 3 − and H 2 O (log(K N 3 − /K H 2 O )) change more than the solvolytic reactivities (log K solv ) of their rather reactive precursors RCl.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1409c3307a5ff190d4a2f23d7df5d0a1 https://doi.org/10.1016/s0040-4039(00)86948-8 Zobrazit plný text záznamu