Synthetic routes to butadienyl complexes. Double addition of methylene to an acetylide and hydrometallation of an ene–yne. X-Ray crystal structure of [Fe2(CO)5{µ-η2,η3-H2CC(Me)CCH2}(µ-PPh2)]

Autor:	Shane A. MacLaughlin, Nicholas J. Taylor, Susan M. Breckenridge, Arthur J. Carty
Rok vydání:	1991
Předmět:	chemistry.chemical_compound chemistry Stereochemistry Acetylide X-ray Molecular Medicine Molecule Crystal structure Methylene Medicinal chemistry Ene reaction
Zdroj:	J. Chem. Soc., Chem. Commun.. :1718-1720
ISSN:	0022-4936
DOI:	10.1039/c39910001718
Popis:	Binuclear butadienyl complexes [Fe2(CO)5{µ-η2,η3-H2CC(R)CCH2}(µ-PPh2)](R = But, Me) have been synthesized via double addition of CH2 fragments to an acetylide in [Fe2(CO)6(µ-η1,η2-CCBut)(µ-PPh2)] or hydrometallation of the ene–yne CH2C(Me)CCH with [HFe2(CO)7(µ-PPh2)].
Databáze:	OpenAIRE
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