MAGNETIC AND ELECTRIC BEHAVIOR OF IRON IONS IN THE 3B2OCAO GLASS MATRIX

Autor: V. Ioncu, P. Păşcuţă, I. Ardelean
Rok vydání: 2001
Předmět:
Zdroj: Modern Physics Letters B. 15:1445-1453
ISSN: 1793-6640
0217-9849
DOI: 10.1142/s0217984901003378
Popis: Magnetic susceptibility and electric resistivity measurements have been performed on x Fe 2 O 3 · (100-x)[3 B 2 O 3· CaO ] glasses with 0 5 mol% the iron ions participate in the negative superexchange interaction. From Curie constant values we have established that in these glasses both Fe 2+ and Fe 3+ ions are present, which explains their magnetic and electric behavior. The electrical resistivity and the conductivity activation energy decreases with the Fe 2 O 3 content. In order to analyze the electrical data, we have considered, in these glasses, a polaronic model for conduction.
Databáze: OpenAIRE