Synthesis and characterization of polyaniline–Fe@C magnetic nanocomposite powder
| Autor: | Ioan Stamatin, A.-M. Niculescu, G. Prodan, A. Iordache, Alina Ilie, I. Sandu, I. Morjan, Eugeniu Vasile, Florian Dumitrache, C.T. Fleaca |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Materials science
General Physics and Astronomy Nanoparticle Infrared spectroscopy 02 engineering and technology 010402 general chemistry 01 natural sciences chemistry.chemical_compound symbols.namesake Polyaniline Composite material Nanocomposite Surfaces and Interfaces General Chemistry Coercivity 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences Surfaces Coatings and Films chemistry Chemical engineering Polymerization Transmission electron microscopy symbols 0210 nano-technology Raman spectroscopy |
| Zdroj: | Applied Surface Science. 374:213-221 |
| ISSN: | 0169-4332 |
| Popis: | We report the synthesis of novel magnetic nanocomposite based on polyaniline (PANI) matrix and Fe–C nanoparticles. These hydrophobic Fe–Fe x C@C nanoparticles (having diameters under 20 nm) were synthesized by laser pyrolysis from Fe(CO) 5 and C 2 H 4 /H 2 and dispersed in water using sodium carboxymethylcellulose, followed by the PANI coating using ultrasonication-assisted oxidative polymerization of aniline hydrochloride. The structure of the resulted composite was characterized by Transmission Electron Microscopy, X-ray diffraction and also by Raman and Infrared spectroscopy. The composite powder shows ferromagnetic behavior with low coercivity and 6.4 emu/g saturation magnetization, having also electric and electrochemical behavior similar with pure PANI reference. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect