Kinetic analysis of photoelectrochemical hydrogen evolution over p-type silicon in acidic aqueous solutions of electrolytes

Autor:	S. D. Babenko, A. A. Balakai, A. G. Lavrushko, Yu. L. Moskvin, S. N. Shamaev
Rok vydání:	2000
Předmět:	Photoexcitation Photocurrent Aqueous solution Silicon chemistry Chemical physics Photoelectrochemistry Inorganic chemistry chemistry.chemical_element Charge density General Chemistry Electrolyte Current density
Zdroj:	Russian Chemical Bulletin. 49:1707-1711
ISSN:	1573-9171 1066-5285
DOI:	10.1007/bf02496338
Popis:	The kinetics of photoelectrochemical hydrogen evolution at p-Si single crystals in acidic aqueous solutions of electrolytes under pulse photoexcitation was studied. Despite a low stability of the silicon surface under the experimental conditions, a distinct interrelation between the characteristic time of interfacial charge transfer and stationary current was found. The determination of the characteristic transfer time does not need the detailed elaboration of generation-recombination processes in the semiconductor. The steady-state current density was shown to be determined both for the dark current and photocurrent by the surface charge density.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::13cd2fb84ec7ddac3d24ab19f30cd5cf https://doi.org/10.1007/bf02496338 Zobrazit plný text záznamu Full text from SpringerLink