SYNTHESIS AND CHARACTERIZATION OF MANGANESE(IV) COMPLEXES DERIVED FROM THE DIRECT REACTION OF MANGANESE(II) ACETATE TETRAHYDRATE WITH OXALOYLDIHYDRAZIDE AND 2-HYDROXY-1-NAPHTHALDEHYDE

Autor:	Ram A. Lal, Samhita Bhaumik, Jayanta Chakraborty, Arvind Kumar, Syamal Adhikari
Rok vydání:	2002
Předmět:	Ethanol Tetrahydrate Chemistry Manganese(II) acetate Inorganic chemistry chemistry.chemical_element Manganese Inorganic Chemistry chemistry.chemical_compound Pyridine Direct reaction Physical and Theoretical Chemistry Spectral data Template method pattern Nuclear chemistry
Zdroj:	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 32:81-96
ISSN:	1532-2440 0094-5714
DOI:	10.1081/sim-120013148
Popis:	Manganese(IV) complexes of the composition [Mn(L)(A)2]·2H2O (where H4L=bis(2-hydroxy-1-naphthaldehyde)oxaloyldihydrazone and A=H2O (1), pyridine (py) (2), 2-picoline (2-pic) (3), 3-picoline (3-pic) (4), 4-picoline (4-pic) (5)) have been synthesized in ethanol by the template method directly from manganese(II) acetate, oxaloyldihydrazine (H2oxh) and 2-hydroxy-1-naphthaldehyde. The complexes have been characterized by elemental analyses, thermoanalytical, molecular weight and molar conductance data. The structural assessment of the complexes has been carried out on the basis of magnetic moment, electronic, IR and ESR spectral data.
Databáze:	OpenAIRE
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