Oxarhodaborane chemistry: the formation of [µ-9,9′-O-{5-(η5-C5Me5)-nido-5-RhB9H12}2] and [7-(η5-C5Me5)-10-(NEt3)-nido-7, 12-RhOB10H10] from [nido-(η5-C5Me5)RhB10H13Cl]

Autor:	Evert J. Ditzel, John D. Kennedy, Hayat Fowkes, Peter MacKinnon, Mark Thornton-Pett, Norman N. Greenwood, Xavier L. R. Fontaine, Zhu Sisan
Rok vydání:	1990
Předmět:	chemistry.chemical_compound Crystallography chemistry Stereochemistry X-ray crystallography Molecular Medicine Molecule Crystal structure Triethylamine BORO
Zdroj:	J. Chem. Soc., Chem. Commun.. :1692-1694
ISSN:	0022-4936
Popis:	Chromatography in air on silica of the nido eleven-vertex metallaborane [(η5-C5Me5)RhB10H13Cl]2, yields the µ-9,9′-oxo-bridged bis(nido-5-rhodadecaboranyl) species [{(η5-C5Me5)RhB9H12}2O]3, whereas treatment with NEt3 before exposure to air and chromatography on silica results in the novel contiguous nido twelve-vertex oxarhodadecaborane [7-(η5-C5Me5)10-(NEt3)-nido-7,12-RhOB10H10]4.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::13980f24321c0e2c382c8b64982faec0 https://doi.org/10.1039/c39900001692 Zobrazit plný text záznamu