New 13-aza baccatins

Autor: Maristella Colombo, E. Arlandini, Maria Menichincheri, Vittorio Pinciroli, Walter Ceccarelli, Nicola Mongelli, Ermes Vanotti, Domenico Fusar-Bassini, L Franzoi
Rok vydání: 1997
Předmět:
Zdroj: Tetrahedron Letters. 38:3301-3304
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00591-1
Popis: Upon treatment of 7-triethylsilyl-10, 13-dideoxy-13-imino baccatin III ( 2 ) subsequently with diazomethane and m-chloroperbenzoic acid a few novel derivatives, namely methylimine 3 and oximes 4 and 5 , were obtained. Interestingly, 4 is characterized by the hydroxyl at position 14 .
Databáze: OpenAIRE