Fluorine substitution effect in bis(imino)pyridine cobalt complex in propylene oligomerization

Autor:	Roberto F. de Souza, Rafael Stieler, Daniel Thiele, Cristiano Favero, Isabel Vicente, Eduardo Miraglia Carvalho, Anna Paula Rodrigues Ehlert, Katia Bernardo-Gusmão, Michèle Oberson de Souza
Rok vydání:	2017
Předmět:	inorganic chemicals Methylaluminoxane chemistry.chemical_element General Chemistry 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Pyridine Fluorine Organic chemistry Cobalt
Zdroj:	Catalysis Today. 296:272-276
ISSN:	0920-5861
DOI:	10.1016/j.cattod.2017.04.005
Popis:	Two bis(imino)pyridine cobalt complexes have been synthesized, the dichlorido-(2,6-bis[1-(phenylimine)ethyl]pyridine)cobalt(II) ([Co-NNNPhH]) and the dichlorido-(2,6-bis[1-(2-trifluoromethyl-4-fluorophenylimine)ethyl]pyridine)cobalt(II) ([Co-NNNPhF]) and used as catalyst precursor in association with methylaluminoxane (MAO) as cocatalyst in propylene oligomerization. The presence of a fluorine group in [Co-NNNPhF] have been investigated and compared to those of [Co-NNNPhH] regarding the catalytic properties in propylene oligomerization and the structure of the complexes. The correlation of the catalytic properties of the cobalt complexes and their structures have been evidenced.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::137e48dc972a1d334f8554980320f593 https://doi.org/10.1016/j.cattod.2017.04.005 Zobrazit plný text záznamu Full Text from ScienceDirect