The thermal decomposition of doped ammonium perchlorate

Autor:	I. Pelly
Rok vydání:	1982
Předmět:	Thermal decomposition Inorganic chemistry Doping Condensed Matter Physics Ammonium perchlorate Decomposition Ion Catalysis chemistry.chemical_compound Electron transfer chemistry Qualitative inorganic analysis Physical and Theoretical Chemistry Instrumentation
Zdroj:	Thermochimica Acta. 55:27-34
ISSN:	0040-6031
DOI:	10.1016/0040-6031(82)87004-4
Popis:	The thermal decomposition of ammonium perchlorate doped with Cu 2+ , Mn 2+ , Co 2+ and Fe 3+ (with and without H + ) was studied using DTA and TG. Small concentrations of these ions inhibit the decomposition by eliminating the first exothermic peak. At higher concentrations, a catalyzed decomposition is observed. Either the influence of the doping ions on the mechanism of the thermal decomposition is different from that of added oxides or a modification of the electron transfer mechanism is needed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::137af985f71d04ca1d6830b55321e276 https://doi.org/10.1016/0040-6031(82)87004-4 Zobrazit plný text záznamu