ChemInform Abstract: The Reactions of Xenon Difluoride with ′Inert′ Solvents

Autor:	Richard L. Powell, P. J. Townson, Eric G. Hope, John H. Holloway, W. W. Dukat
Rok vydání:	2010
Předmět:	Reaction rate chemistry.chemical_compound Chloroform chemistry Hydrogen Xenon difluoride chemistry.chemical_element General Medicine Photochemistry Acetonitrile Dibromomethane Dichloromethane Catalysis
Zdroj:	ChemInform. 25
ISSN:	0931-7597
DOI:	10.1002/chin.199446090
Popis:	The reactions of XeF2 with a variety of organic solvents are described. XeF2 is foundto undergo both hydrogen- and chlorine-fluorine exchange over a relatively short timescalewith chloroform, dichloromethane and dibromomethane. XeF2 reacts very slowly withtetrachloromethane and fluorotrichloromethane, although the addition of a catalytic amountof HF increases the rate of reaction considerably. XeF2 dissolves in acetonitrile withnegligible reaction to the extent of 2.25 mol kg−1.
Databáze:	OpenAIRE
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