NaI-Catalyzed Oxidative Amination of Aromatic Sodium Sulfinates: Synergetic Effect of Ethylene Dibromide and Air as Oxidants

Autor:	Zhengyin Du, Qin-Shan Xu, Ming-Peng Li, Quan-Zhou Li, Helmut M. Hügel, Fu Ying
Rok vydání:	2018
Předmět:	010405 organic chemistry Chemistry Sodium Ethylene Dibromide Organic Chemistry chemistry.chemical_element Oxidative phosphorylation 010402 general chemistry Iodine 01 natural sciences 0104 chemical sciences Catalysis Organic chemistry Oxidative coupling of methane Physical and Theoretical Chemistry Amination
Zdroj:	European Journal of Organic Chemistry. 2018:6966-6970
ISSN:	1434-193X
DOI:	10.1002/ejoc.201801386
Popis:	A novel NaI-catalyzed oxidative amination of sodium sulfinates, employing both ethylene dibromide (EDB) and air as the oxidants, is described. EDB was first demonstrated to be a promising mild organic oxidant that in air, converted NaI into molecular iodine to promote the cross-coupling reactions of aromatic sodium sulfinates with amines to produce arylsulfonamides. Mechanistic studies indicated that a radical pathway might be involved in the reaction process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::136e5ebe202be1f96d1e2f0f300fa9f3 https://doi.org/10.1002/ejoc.201801386 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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