Product vibrational distributions and collision energy dependence of chemiluminescent reactions of group IVA elements with O2, N2O, and NO2

Autor:	C. C. Fang, J. H. Wang, J. M. Parson, B. S. Cheong
Rok vydání:	1990
Předmět:	chemistry.chemical_classification Triatomic molecule General Physics and Astronomy Chemical reaction Diatomic molecule Spectral line chemistry Yield (chemistry) Excited state Physics::Chemical Physics Physical and Theoretical Chemistry Atomic physics Inorganic compound Molecular beam
Zdroj:	The Journal of Chemical Physics. 92:4839-4848
ISSN:	1089-7690 0021-9606
DOI:	10.1063/1.457701
Popis:	Computer simulations of the observed spectra in reactions of group IVA elements with oxygen donors yield information on the product vibrational distributions in the electronically excited states of group IVA oxides. The observed vibrational distributions have been compared with the prior predictions. While the vibrational distributions resulting from the Ge2+O2 reaction show statistical behavior, those of products formed in the Si+N2O reaction are found to be much hotter than the prior distributions. Also, time‐of‐flight studies have been conducted to determine the collision energy dependence of the reactive rate coefficients and the cross sections for these chemiluminescent reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::1367114558e5f521ed3d3d84dbf6ab41 https://doi.org/10.1063/1.457701 Zobrazit plný text záznamu