Effect of HF Modification on the Catalytic Properties of Ferrospheres in the Oxidative Coupling of Methane
| Autor: | Alexander G. Anshits, L. A. Solov’ev, E. V. Rabchevskii, N. N. Anshits, N. P. Kirik |
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| Rok vydání: | 2019 |
| Předmět: |
Ethylene
010405 organic chemistry Chemistry General Chemistry Hematite 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Computer Science Applications chemistry.chemical_compound Chemical engineering Modeling and Simulation Yield (chemistry) visual_art Phase (matter) visual_art.visual_art_medium Dehydrogenation Oxidative coupling of methane Selectivity |
| Zdroj: | Kinetics and Catalysis. 60:196-204 |
| ISSN: | 1608-3210 0023-1584 |
| DOI: | 10.1134/s0023158419020034 |
| Popis: | The effect of the HF modification of ferrospheres separated from fly ash after the combustion of brown coal on their chemical, phase compositions and catalytic properties in the oxidative coupling of methane was studied. The modification led to a change in the phase composition in comparison with that of the initial ferrospheres: a CaF2 phase appeared, the hematite phase content increased, and the ferrospinel content decreased. The yield of C2 hydrocarbons at 750°C increased by a factor of 1.5–2.0, and the fraction of ethylene in them increased to 30 or 65% at 750 or 850°C, respectively. It was assumed that an increase in the efficiency of HF-modified ferrospheres in the formation of ethane and its dehydrogenation into ethylene was due to the formation of oxyfluoride-type active sites. The pyrohydrolysis of fluorine-containing catalyst components at 850°C due to interaction with water vapor in a reaction atmosphere led to the formation of systems active in deep oxidation; this manifested itself in a sharp decrease in selectivity for the formation of C2 hydrocarbons and an increase in selectivity for CO2. |
| Databáze: | OpenAIRE |
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