Interaction of thiirene 1,1-dioxides with transition metal complexes
| Autor: | J. P. Visser, D.N. Reinhoudt, C. G. Kouwenhoven |
|---|---|
| Rok vydání: | 1973 |
| Předmět: |
Organic Chemistry
chemistry.chemical_element Substrate (chemistry) Photochemistry Biochemistry Sulfur Decomposition Metal sulfur dioxide complex Thiirene Inorganic Chemistry Metal chemistry.chemical_compound chemistry Transition metal visual_art Polymer chemistry Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry |
| Zdroj: | Journal of Organometallic Chemistry. 57:403-413 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)86621-8 |
| Popis: | The decomposition of thiirene 1,1-dioxides into sulphur dioxide and the corresponding acetylenes is catalysed by certain transition metal complexes [Pd0 Pt0 and Ir1]. The metal complexes of the substrate are key intermediates in the decomposition. A possible pathway is suggested. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|