Supramolecular Assemblies, Luminescence and Anion Exchange of Helical Pb(II) Complexes Based on Enantiomeric N-(2-pyridylmethyl) Alanine Ligands

Autor:	Qi Zhang, Chen Chen, Hai Zhu, Bao-Hua Qu, Zhi-Hui Zhang
Rok vydání:	2016
Předmět:	Alanine Ion exchange 010405 organic chemistry Stereochemistry Chemistry Polymer chemistry Supramolecular chemistry General Chemistry Enantiomer 010402 general chemistry Luminescence 01 natural sciences 0104 chemical sciences
Zdroj:	Journal of Chemical Research. 40:607-613
ISSN:	2047-6507 1747-5198
DOI:	10.3184/174751916x14738569571337
Popis:	Two pairs of PbII coordination polymers have been synthesised using pyridine-functionalised amino acid derivatives N-(2-pyridylmethyl)-L(D)-alanine hydrochlorides [(L-Hpala)Cl or (D-Hpala)Cl] and PbII salts. Their X-ray structures confirm their formulations as [Pb(L-pala) (NO3)]n, [Pb(D-pala)(NO3)]n, [Pb(L-pala)(Cl)]n and [Pb(D-pala)(Cl)]n. They show similar coordination environments of PbII cations with two kinds of five-membered chelating rings, which are further assembled into 1D helical chains through the bridging carboxylates from amino acids. Thermal and fluorescent properties of these complexes have also been investigated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::134e331f64cb49fb1ba7b60bf4d50207 https://doi.org/10.3184/174751916x14738569571337 Zobrazit plný text záznamu Plný text ve formátu PDF