Studies on dynamic mechanical and mechanical properties of vinyloxyaminosilane grafted ethylene propylene diene terpolymer/linear low density polyethylene (EPDM-g-VOS/LLDPE) blends
| Autor: | M. Suresh Chandra Kumar, Arun Anand Prabu, Muthukaruppan Alagar |
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| Rok vydání: | 2003 |
| Předmět: |
Materials science
Polymers and Plastics EPDM rubber Organic Chemistry technology industry and agriculture General Physics and Astronomy Ethylene propylene rubber Dynamic mechanical analysis Linear low-density polyethylene Crystallinity Ultimate tensile strength Dynamic modulus Materials Chemistry Polymer blend Composite material |
| Zdroj: | European Polymer Journal. 39:805-816 |
| ISSN: | 0014-3057 |
| Popis: | The dynamic mechanical properties of vinyloxyaminosilane grafted ethylene propylene diene terpolymer/linear low density polyethylene (EPDM-g-VOS/LLDPE) blends have been evaluated with special reference to the effect of blend ratio. It has been found that increasing the proportion of LLDPE in the blends decreases the Tg values and increases the storage modulus (E′) and loss modulus (E′′) due to increase in crystallinity. A gradual increase in the values of tanδmax is observed for the blends with increase in EPDM-g-VOS concentration, which indicates that no phase inversion occurs. But however the higher increase in tanδmax after 50 wt.% of EPDM-g-VOS composition is due to small change in crystallinity and is ascertained by SEM micrographs. Mechanical properties such as tensile strength, Young’s modulus and hardness increase with increases in LLDPE concentration in the blends and with dicumyl peroxide (DCP) concentration whereas the values of elongation at break are decreased with increase in LLDPE and DCP concentration. |
| Databáze: | OpenAIRE |
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