Solvent/OSDA-free interzeolite transformation of FAU into CHA zeolite with quantitative yield
| Autor: | Norikazu Nishiyama, Shunsuke Tanaka, Yuichiro Hirota, Manabu Miyamoto, Sana Miyagawa, Yasunori Oumi, Koji Miyake |
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| Rok vydání: | 2019 |
| Předmět: |
Crystal transformation
Materials science Silicon chemistry.chemical_element 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 0104 chemical sciences Solvent Adsorption chemistry Chemical engineering Mechanics of Materials Yield (chemistry) General Materials Science 0210 nano-technology Zeolite Dissolution |
| Zdroj: | Microporous and Mesoporous Materials. 278:219-224 |
| ISSN: | 1387-1811 |
| Popis: | An efficient and simple methodology was proposed to synthesize CHA zeolite without the use of solvent and OSDA. The synthesis strategy is based on a mechanochemical-assisted interzeolite transformation using only Na-type FAU zeolite and KOH as starting materials, for ease of handling and large-scale production. The role of KOH on crystal transformation behaviors and adsorption characteristics of the obtained CHA zeolite were investigated. The important factor was the loading KOH into the cages of starting FAU zeolite with adjusted appropriate amount. In this method, vapor-solid interzeolite transformation occurs by local rearrangement of silicon and aluminum species without accompanying macroscopic dissolution of FAU zeolite, resulting in formation of CHA zeolite maintaining the Si/Al ratio of the starting FAU zeolite. |
| Databáze: | OpenAIRE |
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