Unsymmetric N-heterocyclic carbene ligand enabled nickel-catalysed arylation of bulky primary and secondary amines
| Autor: | Zi-Chao Wang, Yan-Yu Li, Shuo-Qing Zhang, Xin Hong, Shi-Liang Shi |
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| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Chemical Science. 14:4390-4396 |
| ISSN: | 2041-6539 2041-6520 |
| DOI: | 10.1039/d3sc00492a |
| Popis: | A general and efficient Ni-catalysed arylation of bulky primary and secondary amines with aryl chlorides or phenol derivatives is described. DFT studies suggest that unsymmetric bulky and flexible NHC ligand is critical to promote this reaction. |
| Databáze: | OpenAIRE |
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