Observation of the development of the electronic structure ofC60films from submonolayer coverage to two and three dimensionality

Autor:	Si-hua Lü, Gu Zn, Han Rs, Liu Fq, Sicheng Wu, Jun Yao, Xun K, Deng Jz, Wang Zq
Rok vydání:	1993
Předmět:	Delocalized electron Materials science Fullerene Condensed matter physics Electronic correlation Photoemission spectroscopy Monolayer Molecular orbital Electronic structure Thin film Molecular physics
Zdroj:	Physical Review B. 47:13830-13834
ISSN:	1095-3795 0163-1829
Popis:	The electronic structure of C 60 films deposited on Sn substrates has been studied by UV and x-ray photoemission spectroscopy. In contrast with the tight-binding approximation, for submonolayer amounts of C 60 films the peaks derived from the top two occupied molecular orbitals are not narrowed but broadened by 0.3 eV in comparison with solid C 60 . This indicates that the delocalization of electrons in the top two π bands is weak, and the peak widths do not reflect the true band dispersion. For approximately one monolayer (ML) of C 60 film, x-ray photoemission studies of C 1s core levels reveal a feature centered at 22 eV below the main peak
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::130dc5a169527f19d881974733d57983 https://doi.org/10.1103/physrevb.47.13830 Zobrazit plný text záznamu