A novel diastereoselective synthesis of chiral, non-racemic unsymmetrical thioacetals using silicon-induced Pummerer-type reaction

Autor:	Norio Shibata, Kouzou Matsumoto, Shigekazu Fujita, Yasuyuki Kita, Michiyo Gyoten
Rok vydání:	1995
Předmět:	inorganic chemicals Silicon Chemistry organic chemicals Organic Chemistry Drug Discovery health occupations polycyclic compounds chemistry.chemical_element heterocyclic compounds Biochemistry Combinatorial chemistry Catalysis
Zdroj:	Tetrahedron Letters. 36:109-112
ISSN:	0040-4039
DOI:	10.1016/0040-4039(94)02178-e
Popis:	Chiral, non-racemic sulfoxides were reacted with thiols and BSA in the presence of a catalytic amount of TMSOTf in MeCN at rt overnight to give the corresponding chiral, non-racemic anti-thioacetals with high diastereoselectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::12f6c45ff34b20ce1fd0ba66d92868f1 https://doi.org/10.1016/0040-4039(94)02178-e Zobrazit plný text záznamu Full Text from ScienceDirect