Oxidation of white phosphorus by peroxides in water
| Autor: | G. S. Polimbetova, R. R. Abdreimova, D. N. Akbaeva |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
White Phosphorus
Phosphorus Radical Inorganic chemistry chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Peroxide 0104 chemical sciences Homolysis Solvent chemistry.chemical_compound chemistry Physical and Theoretical Chemistry Phosphorous acid 0210 nano-technology Hydrogen peroxide |
| Zdroj: | Russian Journal of Physical Chemistry A. 91:1873-1876 |
| ISSN: | 1531-863X 0036-0244 |
| Popis: | A mixture of hypophosphorous, phosphorous, and phosphoric acids is formed during the anaerobic oxidation of white phosphorus by peroxides [ROOН; R = Н, 3-ClC6H4CO, (СН3)3С] in water. The rate of reactions grows considerably upon adding nonpolar organic solvents. The activity series of peroxides and solvents are determined experimentally. NMR spectroscopy shows that the main product of the reaction is phosphorous acid, regardless of the nature of the peroxide and solvent. A radical mechanism of oxidation of white phosphorus by peroxides in water is proposed. It is initiated by the homolysis of peroxide with the formation of НO∙ radicals that are responsible for the homolytic opening of phosphoric tetrahedrons. Further oxidation and stages of the hydrolysis of intermediate phosphorus-containing compounds yield products of the reaction. |
| Databáze: | OpenAIRE |
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