Cationic palladium(II)–acetylacetonate complexes bearing α-diimine ligands as catalysts in norbornene polymerization

Autor:	V. S. Tkach, P.A. Abramov, M. V. Bykov, M.V. Pahomova, D. S. Suslov
Rok vydání:	2015
Předmět:	Process Chemistry and Technology Palladium(II) acetylacetonate Cationic polymerization chemistry.chemical_element General Chemistry Catalysis chemistry.chemical_compound chemistry Polymerization Polymer chemistry Organic chemistry Addition polymer Diimine Palladium Norbornene
Zdroj:	Catalysis Communications. 67:11-15
ISSN:	1566-7367
DOI:	10.1016/j.catcom.2015.03.022
Popis:	A variety of palladium(II)–acetylacetonate complexes bearing α-diimine ligands were synthesized by the reaction of [Pd(acac)(MeCN)2]BF4 with N⁀N ligands. When activated with BF3·OEt2, these complexes provide access to a new class of alkylating agent free Pd–diimine catalyst systems. Catalyst screening for the vinyl addition polymerization of norbornene showed their high activities of 102–104 kgpol molcat− 1 h− 1.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::12f3c16541fff2276b5fa4a34debdb4c https://doi.org/10.1016/j.catcom.2015.03.022 Zobrazit plný text záznamu Full Text from ScienceDirect