Periodic behaviour in continuous emulsion polymerization systems

Autor:	D.C. Blackley, D.T. Birtwistle, E.F. Jeffers
Rok vydání:	1980
Předmět:	Polymers and Plastics Polymerization Chemistry Organic Chemistry Polymer chemistry Materials Chemistry Emulsion polymerization Thermodynamics Steady state (chemistry) Sustained oscillations
Zdroj:	Polymer. 21:332-337
ISSN:	0032-3861
DOI:	10.1016/0032-3861(80)90277-3
Popis:	A modification of the model of Brooks for a non-steady-state continuous emulsion polymerization reaction has been examined to ascertain whether it permits the possibility of (a) periodic fluctuations in rate of polymerization in the vicinity of the steady state, and (b) sustained fluctuations in rate of polymerization in any physically-attainable condition. We conclude that neither of these possibilities is realizable in reaction systems which conform to the model which has been considered. Nor are sustained oscillations possible in reaction systems which conform to certain variants of the model.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::12da46f4c71174e84f9e6a841aaffe3b https://doi.org/10.1016/0032-3861(80)90277-3 Zobrazit plný text záznamu