Synthesis and properties of polysiloxanes containing mixed functional groups

Autor: Hieronim Maciejewski, Katarzyna Dopierała, Joanna Karasiewicz, Krystyna Prochaska, Michał Dutkiewicz, Agnieszka Dutkiewicz
Rok vydání: 2014
Předmět:
Zdroj: Reactive and Functional Polymers. 83:144-154
ISSN: 1381-5148
Popis: An effective synthesis of polysiloxanes containing mixed functional groups was carried out using consecutive hydrosilylation of two different olefins. With the functionalization of polysiloxanes, we sought to obtain derivatives containing fluoroalkyl groups (with hydrophobic properties) and reactive groups capable of attaching a polysiloxane to the surface. Glycidyl and trimethoxysilyl groups were chosen for the study. All of the obtained derivatives were isolated and spectroscopically characterized. In the next stage of the study, glass plates were modified with functionalized polysiloxanes, both alone and with added silica sol, and their hydrophobic properties were determined by measuring contact angles. From the results, we determined the effect of functionalized polysiloxane structure on the hydrophobic properties of polysiloxane-modified surfaces.
Databáze: OpenAIRE