Copper(II) and palladium(II) complexes with tridentate NSO donor Schiff base ligand: Synthesis, characterization and structures
| Autor: | Ankita Solanki, Sujit Baran Kumar, Suman Kundu |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Schiff base
010405 organic chemistry Stereochemistry Ligand Organic Chemistry chemistry.chemical_element Crystal structure 010402 general chemistry 01 natural sciences Copper Square pyramidal molecular geometry 0104 chemical sciences Analytical Chemistry Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Molecule Single crystal Spectroscopy Palladium |
| Zdroj: | Journal of Molecular Structure. 1143:163-167 |
| ISSN: | 0022-2860 |
| DOI: | 10.1016/j.molstruc.2017.04.081 |
| Popis: | Mononuclear copper(II) complex [CuL2] and palladium(II) complexes [Pd(X)L] where X = benzoate(bz) or salicylate(sal) and HL = 2-(methylthio)phenylimino)methyl)phenol, a Schiff base ligand with NSO coordination sites have been synthesized and characterized by microanalyses, IR, UV–Visible spectra, conductivity measurement and magnetic studies. Crystal structures of all the complexes have been solved by single crystal X-ray diffraction studies and showed that there are two molecules in a unit cell in the [CuL2] complex - one molecule has square planar geometry whereas second molecule has distorted square pyramidal geometry and palladium(II) complexes have distorted square planar geometry. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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