Novel sulfonate containing ET based synmetals
| Autor: | A. M. Kini, Seddon Y. Thomas, E. Morales, Urs Geiser, Jennifer L. O'Malley, James D. Dudek, Jack M. Williams, James P. Parakka, Gary L. Gard, B. H. Ward, John A. Schlueter, Hsien-Hau Wang |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
Ethylene
Hydrogen bond Mechanical Engineering Inorganic chemistry Metals and Alloys Crystal structure Condensed Matter Physics Electronic Optical and Magnetic Materials Metal chemistry.chemical_compound symbols.namesake Sulfonate chemistry Mechanics of Materials visual_art X-ray crystallography Polymer chemistry Materials Chemistry visual_art.visual_art_medium symbols Molecule Raman spectroscopy |
| Zdroj: | Synthetic Metals. 102:1666-1669 |
| ISSN: | 0379-6779 |
| DOI: | 10.1016/s0379-6779(98)00264-1 |
| Popis: | Electrocrystallization of ET in the presence of aromatic and aliphatic sulfonate anions has led to many new ET salts. These new ET based sulfonate complexes are characterized with use of x-ray diffraction, four-probe conductivity measurements, ESR and Raman spectroscopies. A new κ(4 × 4) donor packing motif was observed in (ET)2(C6H5CH2SO3)(H2O). Strong hydrogen bonding between the sulfonate anion S-O and the donor ethylene C-H provides the driving force for the ET salt formation. Many of these new sulfonate salts are highly conductive with some remaining metallic to ~ 4 K. |
| Databáze: | OpenAIRE |
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