Contribution of solid electrochemical techniques to high temperature oxidation studiest†
| Autor: | Yasutoshi Saito |
|---|---|
| Rok vydání: | 2000 |
| Předmět: |
Materials science
Mechanical Engineering Metals and Alloys Analytical chemistry Partial pressure Electrolyte Condensed Matter Physics Thermal diffusivity Electrochemistry Metal Carbon dioxide sensor Chemical engineering Mechanics of Materials Electrical resistivity and conductivity visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Oxygen sensor |
| Zdroj: | Materials at High Temperatures. 17:471-481 |
| ISSN: | 1878-6413 0960-3409 |
| Popis: | Solid electrochemical techniques have been applied to high temperature oxidation studies in experiments and concept. The principles of the parabolic oxidation law and solid electrolyte cells have been derived from the same origin developed by Carl Wagner. Oxygen sensors and pumps using solid electrolyte cells are very useful for the study of oxidation kinetics as a function of oxygen partial pressure. A tip-type solid electrolyte CO2 sensor is very sensitive to detect the evolution of CO2 gas, and is useful for the analysis of high temperature oxidation of metal carbides. A mechanistic model proposed for the reactive element effect of chromia-forming alloys has been confirmed by the measurements and data analysis of thermodynamic properties, electrical conductivity and diffusivity of YCrO3 on the basis of solid electrochemical techniques and defect structures. |
| Databáze: | OpenAIRE |
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