Synthesis and structural characterization of a novel bis(silyl) platinum(II) complex bearing SiH3 ligand

Autor:	Wen-Yong Lai, Xing-Ao Li, Shi Wang, Shanghui Ye, Zheng-Feng Huang, Lin-Fang Cui, Lianhui Wang, Yong-Hua Li
Rok vydání:	2014
Předmět:	Inorganic Chemistry Silylation Chemistry Stereochemistry Ligand Organic Chemistry Materials Chemistry chemistry.chemical_element Physical and Theoretical Chemistry Platinum Biochemistry Single crystal Medicinal chemistry
Zdroj:	Journal of Organometallic Chemistry. 749:246-250
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2013.10.006
Popis:	Treatment of (SiH2)(SiMe2tBu)2 (1), (SiH3)SiH(SiMe2tBu)2 (2) with Pt(dcpe)(PEt3)2 (dcpe = Cy2PCH2CH2PCy2) in the ratio of 2:1:1 in one pot leads to a novel complex {(SiH)(SiMe2tBu)2}(SiH3)PtII(dcpe) (3), which is the first example of bis(silyl) platinum(II) complex bearing a SiH3 ligand structurally characterized by single crystal X-ray analysis and multinuclear NMR spectroscopic studies. H2Si(SiMe2tBu)2 for 1, HSi(SiH3)(SiMe2tBu)2 for 2, Pt(dcpe)(SiH3)[SiH(SiMe2tBu)2] for 3 throughout the manuscript.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::129169361517e2524c9d45dd835d8624 https://doi.org/10.1016/j.jorganchem.2013.10.006 Zobrazit plný text záznamu Full Text from ScienceDirect