Thermal and chemical intramolecular N → N acyl-migration in 8-acyl-3, 8-diazabicyclo[3.2.1]octanes

Autor:	C.R. Pasqualucci, G. Cignarella, E. Testa
Rok vydání:	1963
Předmět:	Stereochemistry Chemistry Intramolecular force Organic Chemistry Drug Discovery lipids (amino acids peptides and proteins) Alkali metal Biochemistry Medicinal chemistry
Zdroj:	Tetrahedron. 19:143-148
ISSN:	0040-4020
DOI:	10.1016/0040-4020(63)80016-2
Popis:	The 8-acyl-3,8-diazabicyclo[3.2.1]octanes rearrange by thermal action to 3-acyl-3-8-diazabicyclo[3.2.1]octanes. The N (8) → N (3) acyl-migration is also induced by dilute alkali and by concomitant thermal and acid factors. Attempts to obtain the reverse acyl-migration were unsuccessful.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::128c15a63cc1b3093eac4a4110af820c https://doi.org/10.1016/0040-4020(63)80016-2 Zobrazit plný text záznamu